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Supramolecular Hydrogels with CdS Quantum Dots Incorporated by Host–Guest Interactions

✍ Scribed by Mingyu Guo; Ming Jiang


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
285 KB
Volume
31
Category
Article
ISSN
1022-1336

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✦ Synopsis


Abstract

In this communication, β‐cyclodextrin modified quantum dots were used as a water‐soluble “supramolecular” cross‐linker (SCL) because of its surface's supramolecular activity. The guest monomer‐loaded SCL (mSCL) can be used to copolymerize with water‐soluble monomers leading to transparent hybrid supramolecular hydrogels. This simple and versatile method opens new venues for the preparation of hybrid supramolecular hydrogels and the host–guest chemistry of cyclodextrins.

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## Abstract Detection of an analyte via supramolecular host–guest binding and quantum dot (QD)‐based fluorescence resonance energy transfer (FRET) signal transduction mechanism is demonstrated. Surface patterns consisting of CdSe/ZnS QDs functionalized at their periphery with __β__‐cyclodextrin (__