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Supramolecular Control over the Stereochemistry of Diene Polymers

✍ Scribed by Sadamu Nagahama; Toshihiro Tanaka; Akikazu Matsumoto


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
146 KB
Volume
116
Category
Article
ISSN
0044-8249

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✍ Sadamu Nagahama; Toshihiro Tanaka; Akikazu Matsumoto πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 147 KB

The irradiation dose was 200 kGy at a dose rate of 48.6 kGy h Γ€1 . After irradiation, the polymer was isolated by removal of any remaining monomer with methanol. The polymer yield was determined by gravimetric analysis. NMR, IR, and UV spectra were recorded on a JEOL JMN A-400, JASCO Herschel FT-IR

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## Abstract A novel kind of supramolecular liquid‐crystalline polymer (SLCP) microparticles was successfully fabricated with an azopyridyl polymer and sebacic acid by combining a simple self‐organized precipitation method with hydrogen bonding interactions. Upon slow evaporation of a mixed solution