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Supramolecular Chiral Transcription and Recognition by Mesoporous Silica Prepared by Chiral Imprinting of a Helical Micelle

✍ Scribed by Huibin Qiu; Yoshihisa Inoue; Shunai Che

Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 537 KB
Volume: 48
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.200900303

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✦ Synopsis

Abstract

Let′s twist again: The chirality of a helical propeller‐like micelle has been memorized by functional groups on the mesopore surface of chiral mesoporous silicas. Such imprinted supramolecular chirality can be transcripted to poly(propiolic acid) sodium salt and tetraphenylporphine tetrasulfonic acid (see picture), and recognized by B‐DNA.magnified image

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