✦ LIBER ✦
Supramolecular Assemblies Directed by Hydrogen Bonds and π–π Interactions and Based on N-Heterocyclic-Ligand-Modified β-Octamolybdate – Structure and Catalytic Application in Olefin Epoxidation
✍ Scribed by Juan Du; Jiehui Yu; Jianyuan Tang; Jing Wang; Wenxiang Zhang; Werner R. Thiel; Mingjun Jia
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 353 KB
- Volume
- 2011
- Category
- Article
- ISSN
- 1434-1948
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✦ Synopsis
A series of supramolecular assemblies based on POMs modified by organic ligands, including (Himi) 4 [(imi) 2 (Mo 8 O 26 )]• H 2 O (1), (H 2 bbi) 2 [Mo 8 O 26 ] (2), and (H 2 bbi)[(Hbbi) 2 (Mo 8 O 26 )]•H 2 O (3), were synthesized by a one-step hydrothermal method. All of them are active catalysts for the epox-