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Suppression of spin diffusion in selected frequency bands of nuclear Overhauser spectra

✍ Scribed by Sébastien J. F. Vincent; Catherine Zwahlen; Geoffrey Bodenhausen


Book ID
104662453
Publisher
Springer Netherlands
Year
1996
Tongue
English
Weight
383 KB
Volume
7
Category
Article
ISSN
0925-2738

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✦ Synopsis


A variant of two-dimensional nuclear Overhauser effect spectroscopy (NOESY) is described that yields information about cross-relaxation rates between pairs of spins, while the migration of magnetization through several consecutive steps (spin diffusion via neighboring spins) is largely suppressed. This can be achieved by inserting a doubly-selective inversion pulse in a conventional NOESY sequence.


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Analysis of Spin Diffusion and Cross Cor
✍ P.K. Madhu; Anil Kumar 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 113 KB

The effect of dipole-dipole cross correlations on the net nuclear Overhauser effect (NOE) has been analyzed here for realistic systems by extending the three-spin calculations to four and five spins in order to account for additional cross correlations and spin diffusion. These have been compared wi