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Supported Metallocene Complexes for Ethylene and Propylene Polymerizations: Preparation and Activity

โœ Scribed by Ribeiro, Maria R.; Deffieux, Alain; Portela, Manuel F.


Book ID
120013955
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
399 KB
Volume
36
Category
Article
ISSN
0888-5885

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Synthesis of hetero-bimetallic metalloce
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Five new hetero-bimetallic metallocene complexes were synthesized by the reaction of RCpTiCl 3 and a Si-bridged zirconocene complex in refluxing toluene. They were all well characterized. These complexes activated with methylaluminoxane (MAO) are highly active catalysts for the polymerization of eth