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Supported liquid membrane extraction of urinary trans, trans-muconic acid, a biomarker for benzene exposure

✍ Scribed by Jan Norberg; Degu Tiruye; Lennart Mathiasson; Jan Åke Jönsson


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
110 KB
Volume
25
Category
Article
ISSN
1615-9306

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✦ Synopsis


Supported liquid membrane extraction of urinary trans, trans-muconic acid, a biomarker for benzene exposure

In this study, sample preparation of urinary trans, trans-muconic acid (tt-MA), a minor metabolite and biomarker of benzene, by means of Supported Liquid Membrane (SLM) extraction has been investigated. The sample extract was automatically transferred on-line to an ion exchange chromatographic column and the analytes were detected using a photodiode array detector. Automation of the system was accomplished using a robotic sample preparation processor integrated into the chromatographic system. Detection limits calculated from the baseline noise was in the subppb range, and quantification of tt-MA is safe down to 10 ppb.