Supported cyclopentadienylmetal carbonyl complexes : III. Silica-gel-supported iron and cobalt derivatives
β Scribed by Ferdinand R.W.P. Wild; Guiseppe Gubitosa; Hans H. Brintzinger
- Book ID
- 108351870
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 640 KB
- Volume
- 148
- Category
- Article
- ISSN
- 0022-328X
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In this work the syntheses of covalently grafted C-protected Fe(III)-amino acid (methylesters of L-histidine, L-cysteine and L-cystine) mixed-ligand complexes with two different amino acid esters are described using chloropropylated silica gel as the support. Conditions of the syntheses were systema
The epoxidation of linear and cyclic olefins was catalysed by iron( III), nickel(II) and cobalt(I1) centres immobilized on insoluble polymers. The latter were obtained by reaction of the polymerizable complexes of Fe( III), Ni( II) and Co( II) with 2-(acetoacetoxy)etbyl metbacrylate with acrylamides