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The anodic evolution of oxygen was investigated on the platinum oxide electrode, prepared by a thermal decomposition method, in alkaline solutions; the overvoltage data were reproducible on this electrode. On the basis of reliable mechanistic observations, the most probable path under Langmuir condi
## A&met-Electrochemical properties of ruthenium, particularly the anodic evolution of oxygen and anodic dissolution of ruthenium have been investigated by means of polarization measurements and product analyses. The electrode surface gradually colours black during oxygen evolution. This is due to
The mechanism of the cathodic reduction of oxygen on smooth platinum in 0.5 M H,SO, solution has been studied on the basis of the current efficiency for H,O, formation. H,O, formation occurs at cathode potentials 1680 mV (nhe), whereas the initial rest-potential lies at 960 mV. The current efficien