Donor-acceptor compounds containing a phenylenediamine electron donor and a naphthalene, a cyanobenzene, or a cyanonaphthalene acceptor were studied. The two chromophores are connected by three different bridging units, consisting of CH 2 groups linked to a semiflexible piperidine or piperazine ring
Superexchange-Mediated Charge Separation and Charge Recombination in Covalently Linked Donor—Bridge—Acceptor Systems
✍ Scribed by Michael N. Paddon-Row
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 52 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract We estimate, at a full quantum‐chemical level, the various molecular parameters governing the rate of photoinduced charge generation and charge recombination in model organic structures containing a donor and an acceptor unit in view of the possible use of such systems in organic solar
The process of intramolecular charge separation was studied in three nearly identical donor-bridge-acceptor compounds (1-3) under jet-cooled conditions. Each consists of a vinylcyanonaphthalene group as a powerful electron acceptor and an anilino derivative as an electron donor, separated by a rigid