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Supercritical fluid extraction and chromatography of artemisinin and artemisinic acid. An improved method for the analysis of Artemisia annua samples

✍ Scribed by Marcel Kohler; Werner Haerdi; Philippe Christen; Jean-Luc Veuthey


Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
104 KB
Volume
8
Category
Article
ISSN
0958-0344

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✦ Synopsis


Artemisinin and artemisinic acid were extracted from aerial parts of Artemisia annua by supercritical fluid extraction (SFE) with carbon dioxide modified with 3% (v/v) methanol. The quantitative determination of both compounds was carried out by supercritical fluid chromatography (SFC) coupled with an evaporative light scattering detector (SFC-ELSD). Results obtained by SFE-SFC-ELSD show that this method allows mild extraction conditions and quantitative determination without further purification of the plant extract. In all cases, artemisinin and artemisinic acid were extracted in a higher yield with supercritical carbon dioxide than with liquid-solid extraction.