Supersonic jet spectroscopic detection has been successfully coupled to capillary supercritical fluid chromatography by introduction of the supercritical effluent into a secondary flow of argon, before supersonic expansion of the combined flow through a converging nozzle. At pressures of 6-10 atm, t
✦ LIBER ✦
Supercritical fluid chromatography–supersonic jet spectroscopy: I. Microcolumns and direct expansions
✍ Scribed by John K. Simons; Chung Hang Sin; Norman A. Zabriskie; Milton L. Lee; Steven R. Goates; Steven M. Fields
- Publisher
- John Wiley and Sons
- Year
- 1989
- Tongue
- English
- Weight
- 560 KB
- Volume
- 1
- Category
- Article
- ISSN
- 1040-7685
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A newly designed two-dimensional corona-excited slit nozzle discharge is described and its first applications for direct absorption spectroscopy of molecular ions in a supersonic expansion in the infrared (NO+ ) and far-infrared (N,H+ ). The results are discussed and it will be shown that under the