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Supercritical carbon dioxide as reaction medium: examination of its solvent effects in the near-critical region

โœ Scribed by Ikushima, Yutaka; Saito, Norio; Arai, Masahiko


Book ID
120083672
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
598 KB
Volume
96
Category
Article
ISSN
0022-3654

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The ester syntheses from acyl donors and terpene alcohols catalyzed by Candida cylindracea(CCL) lipase have been carried out in supercritical carbon dioxide(SC-CO2). In the nearcritical region, the rate of esterification showed a sharp maximum and /-terpene esters were stereoselectively synthesized