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Superconductivity and structure of η-Mo3C2

✍ Scribed by K. Yamaura; Q. Huang; E. Takayama-Muromachi

Book ID
104083699
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
264 KB
Volume
468
Category
Article
ISSN
0921-4534

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✦ Synopsis

Local structure of the layered superconductor g-Mo 3 C 2 (T c = 8.5 K) was studied by a neutron diffraction method. The structure comprises a triangular-lattice layer and a block layer, and the layers share a common structure basis of octahedral CMo 6 . We found that the block layer contains non-trivial disorders likely caused by inhomogeneous carbon distribution, while the triangular-lattice layer consists of almost perfect regular octahedra. Thus, the triangular-lattice is probably responsible for the superconductivity.

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