Superconductivity and normal state resistivity of Ba0.6K0.4BiO3: an optical phonon approach
✍ Scribed by D. Varshney; S. Shah; R.K. Singh
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 185 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0749-6036
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✦ Synopsis
We discuss the nature of the pairing mechanism and the physical properties associated with the normal as well as the superconducting state of cubic perovskites Ba 0.6 K 0.4 BiO 3 using the strong coupling theory. An interaction potential which includes the Coulomb, electron-optical phonon and electron-plasmon interactions is developed to elucidate the superconducting state. A model dielectric function is constructed with these interactions fulfilling the f -sum rule. The screening parameter (µ * = 0.26) infers the poor screening of charge carriers. The electron-optical phonon strength (λ) estimated as 0.98 is consistent with an attractive electron-electron interaction and supports the moderate to strong coupling theory. The superconducting transition temperature of Ba 0.6 K 0.4 BiO 3 is then estimated as 32 K. Ziman's formula of resistivity is employed to analyse and compare this with the temperature-dependent resistivity of a single crystal. The estimated contribution from the electron-optical phonon together with the residual resistivity clearly infers a difference when a comparison is made with experimental data. The subtracted data infer a quadratic temperature dependence in the temperature domain (30 ≤ T ≤ 200 K). The quadratic temperature dependence of ρ [= ρ exp -(ρ 0 +ρ e-ph )] is understood in terms of 3D electronelectron inelastic scattering. The presence of these el-el and el-ph interactions allows a coherent interpretation of the physical properties. Analysis reveals that a moderate to strong coupling exists in the Ba 0.6 K 0.4 BiO 3 system and the coupling of electrons with the highenergy optical phonons of the oxygen breathing mode will be a reason for superconductivity. The implications of the above analysis are discussed.
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