Superconducting phase diagram of Nax(H3O)zCoO2 · yH2O
✍ Scribed by Hiroya Sakurai; Kazunori Takada; Takayoshi Sasaki; Eiji Takayama-Muromachi
- Publisher
- Elsevier Science
- Year
- 2007
- Tongue
- English
- Weight
- 124 KB
- Volume
- 460-462
- Category
- Article
- ISSN
- 0921-4534
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✦ Synopsis
Superconducting phase diagram of sodium cobalt oxyhydrate was determined. It was proved that the superconductivity is very sensitive to the isovalent ion exchange between the Na + and H 3 O + ions but rather insensitive to the Co valence, suggesting that e 0 g bands play a crucial role in the occurrence of the superconductivity.
📜 SIMILAR VOLUMES
In cobaltate superconductor Na x (H 3 O) z CoO 2 AE yH 2 O with bilayered hydrate (BLH) structure, Co nuclear magnetic resonance (NMR) measurement was performed to investigate the low-temperature magnetic excitations in magnetic field. The nuclear spin-lattice relaxation rate (1/T 1 ) of Co was meas
We synthesized Na x (H 3 O) z CoO 2 AE y 0 H 2 O samples with various Na/H 3 O ratios but with the constant Co valence of s = +3.40, and measured their magnetic properties to draw phase diagrams of the system. The superconductivity is very sensitive to the Na/H 3 O ratio. With varying x under fixed
We report here the correlation between the water content and superconductivity in Na 0:3 CoO 2 AE yH 2 O under the influences of elevated temperature and cold compression. The X-ray diffraction of the sample annealed at elevated temperatures indicates that intergrowths may exist in the compound at e