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Superacid-Catalyzed Reactions of Pyridinecarboxaldehydes.

✍ Scribed by Douglas A. Klumpp; Yiliang Zhang; Patrick J. Kindelin; Siufu Lau

Publisher: John Wiley and Sons
Year: 2006
Weight: 18 KB
Volume: 37
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200641135

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## Abstract Methyl (2__Z__,6__Z__,10__E__,14__E__)‐ (**3**) and methyl (2__E__,6__Z__,10__E__,14__E__)‐geranylfarnesoate (**4**) were prepared, and then individually cyclized in the presence of the superacid FSO~3~H. In the case of substrate **3**, the scalaranic ester **9** (26%) and the cheilanth