Sum rules for atomic polar and axial tensors from vibronic coupling theory

Evaluation of theories of vibrational ma

Evaluation of theories of vibrational magnetic dipole transition moments using atomic axial tensor sum rules and paramagnetic susceptibilities

✍ P.J. Stephens 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 489 KB

Vibrational magnetic dipole transition moments, and hence rotational strengths and vibrational circular dichroism intensities, are determined by the atomic axial tensors. The electronic contributions to the latter, I&, are related via a sum rule to the paramagnetic susceptibility tensor, ,&. Their a