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Sum frequency generation spectroscopic study of CO/ethylene coadsorption on the Pt(1 1 1) surface and CO poisoning of catalytic ethylene hydrogenation

โœ Scribed by P Chen; K.Y Kung; Y.R Shen; G.A Somorjai


Book ID
117216205
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
704 KB
Volume
494
Category
Article
ISSN
0039-6028

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Structural change of CO adsorbed on Pt(1
โœ Satoshi Katano; Shinsaku Dobashi; Jun Kubota; Ken Onda; Akihide Wada; Satoru S. ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 213 KB

The IR-visible sum-frequency generation (IVSFG) method was used to perform time-resolved vibrational measurements of CO/Pt(1 1 1). Irradiation of intense picosecond laser pulses (35 ps, 1064 nm) resulted in a drop in intensity, redshift, and broadening of the on-top CO stretching peak, followed by r