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Sum-frequency generation in situ study of CO adsorption and catalytic CO oxidation on rhodium at elevated pressures

✍ Scribed by T. Pery; M.G. Schweitzer; H.-R. Volpp; J. Wolfrum; L. Ciossu; O. Deutschmann; J. Warnatz


Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
308 KB
Volume
29
Category
Article
ISSN
1540-7489

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πŸ“œ SIMILAR VOLUMES


Sum Frequency Generation Study of CO Ads
✍ Unterhalt, H. ;Galletto, P. ;Morkel, M. ;Rupprechter, G. ;Freund, H.-J. πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 151 KB

In the present contribution CO adsorption on palladium aggregates was examined with IR-visible sum frequency generation vibrational spectroscopy. Supported Pd nanoparticles of different mean size and surface roughness were prepared by electron beam evaporation on an ordered Al 2 O 3 thin film formed

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The adsorption of carbon monoxide was studied under steady state conditions on smooth rhodium electrodes in 0.5 M H,SO, at room temperature. The coverage with orbon monoxide is equal to saturation coverage between 0.1 and 0.5 V us a hydrogen electrode in the same solution. Above 0.5 V it decreases