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Sulphur-containing metal complexes: XXIII. Synthesis of new complexes containing the Fe2(CO)6S2 butterfly unit. Crystal and molecular structure of [Fe2(CO)6{μ-S2P(C6H4OMe-p)Fe(CO)4}], determined from two different crystal modifications

✍ Scribed by Gert J. Kruger; Simon Lotz; Lorna Linford; Martie Van Dyk; Helgard G. Raubenheimer


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
737 KB
Volume
280
Category
Article
ISSN
0022-328X

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## Abstract A series of mono‐ and disubstituted diiron complexes [(μ‐pdt)Fe~2~(CO)~5~L] [pdt = 1,3‐propanedithiolato; L = PMe~3~ (2), PMe~2~Ph (3PPh~3~ (4), P(OEt)~3~ (5)] and [(μ‐pdt)Fe~2~(CO)~4~L~2~] [L = PMe~2~Ph (6), PPh~3~ (7), P(OEt)~3~ (8)] were prepared as Fe‐only hydrogenase‐active‐site mo