Sulphidomolybdenum(V) complexes with amino acid dithiocarbamates
β Scribed by Vasanthi Lakshmanan; M.R. Udupa; K.S. Nagaraja
- Book ID
- 108428557
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 268 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0277-5387
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Three cationic complexes containing the [Re((V))O](3+) core (general formula [ReO(dien-H)(aa)](+), dien=diethylenetriamine, aa=glycine, alanine, valine) were studied on polycrystalline Au electrodes employing cyclic voltammetry techniques. The electrochemical behavior of the amino acids (aa) was als
Pheriylglycine and phenylalanine react with CS2 in a basic medium to yield the corresponding dithiocarbamates, which react with Ni 2 + and Cu 2 + salts to form complexes of the general formula [Ni(dtc aa)2 ] and [Cu(dtc aa)], respectively (aa = amino acid). Both series of complexes are diamagnetic a