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Sulfuric acid catalyzed rearrangements of 1- and 3-homoadamantanols

โœ Scribed by Janjatovic, Jelena; Skare, Danko; Majerski, Zdenko


Book ID
127170317
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
489 KB
Volume
39
Category
Article
ISSN
0022-3263

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2-(4-Ketoalkyl)cyclopentanones, when subjected to the action of 1 M H 2 SO 4 at reflux, undergo ring cleavage and formation reactions to give 4-(1-cyclopentenyl)butanoic acids. When the starting ring is six-membered instead, a bicyclic enone results. Mechanistic discussion and some experimental test