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Sulfur resistance of Pd complexes with nitrogen and sulfur ligans in hydrogenation reactions

✍ Scribed by Voskresenskaya, T. P. ;Chinakov, V. D. ;Nekipelov, V. M. ;Mashkina, A. V.


Book ID
112685327
Publisher
Springer
Year
1986
Tongue
English
Weight
252 KB
Volume
32
Category
Article
ISSN
0133-1736

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## Abstract Rhodium‐catalyzed hydroboration of 1‐octene and __trans__‐4‐octene with sulfur‐ and nitrogen analogues of catecholborane are demonstrated with the use of in situ ^11^B NMR spectroscopy. Our study shows that the sulfur‐ and nitrogen analogues are significantly less prone to disproportion