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Sulfur monoxide chemistry. Stereochemistry of the thiirane oxide-diene reaction

โœ Scribed by Chao, Peter.; Lemal, David M.


Book ID
127202067
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
380 KB
Volume
95
Category
Article
ISSN
0002-7863

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We report a transformation of benzofurazan oxide (BFO) (1) into 3-substituted quinoxalinel-N-oxides by reaction with various a&unsaturated aldehydes-and ketones in the presence of morpholine. Reaction of 1 eq. BFO, 1.1 eq. trans-4-phenyl-3-buten-2-one (s), and 1.1 eq. morpholine in either acetonitri