In the course of systematic investigation of the isoprenoid cgclization reaction under the action of \*'external" electrophiles such as H + (see, for instance b]) and acyl-or alkyl-cations generated from complexes of type R+ BF4-PI, our attention was turned to electrophilio mercury salts. As was an
β¦ LIBER β¦
Sulfur-containing electrophiles as initiators for cyclization of isoprenoids
β Scribed by M. T. Mustafaeva; M. Z. Krimer; V. A. Smith; A. V. Semenovskii; V. F. Kucherov
- Book ID
- 112421373
- Publisher
- Springer
- Year
- 1972
- Tongue
- English
- Weight
- 68 KB
- Volume
- 21
- Category
- Article
- ISSN
- 1573-9171
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## Abstract The use of Nβacylhydrazones as electrophiles in reactions with nucleophiles has recently made some important advances. NβAcylhydrazones, which can be readily prepared and stored, act as stable imine surrogates in these reactions. The hydrazide products are useful, often chiral building