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Sulfoximine Version of Double Elimination Protocol for Synthesis of Chiral Acetylenic Cyclophanes.

โœ Scribed by Akihiro Orita; De Lie An; Takehiko Nakano; Jayamma Yaruva; Nianchun Ma; Junzo Otera


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
33
Category
Article
ISSN
0931-7597

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Double Elimination Protocol for Synthesi
โœ Akihiro Orita; Daiki Hasegawa; Takehiko Nakano; Junzo Otera ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 123 KB ๐Ÿ‘ 1 views

A new method for constructing 5,6,11,12-tetradehydrodibenzo[a,e]cyclooctene is described on the basis of one-pot double elimination protocol. The target molecule, which is the smallest cyclophane with alternate arylene-ethynylene linkage, is synthesized in 61 % yield through oxidative dimerization o