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Sulfonimidamides: Efficient Chiral Iminoiodane Precursors for Diastereoselective Copper-Catalyzed Aziridination of Olefins

✍ Scribed by Di Chenna, Pablo H.; Robert-Peillard, Fabien; Dauban, Philippe; Dodd, Robert H.


Book ID
118737830
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
57 KB
Volume
6
Category
Article
ISSN
1523-7060

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The preparation of different lN-(arenesulfonyl)iminolphenyliodinanes is described along with an evaluation of their utility as nitrene precursors for the copper-catalyzed aziridination of different olefins. The best results were obtained with p-NO2-Cr, H, flO~=IPh and p-MeO-Ce~I4SO2N=IPh, both of wh