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Sulfinyl moiety as an internal nucleophile. Part 6: Stereospecific synthesis of 3-amino-2-hydroxy-4-phenylbutanoate

✍ Scribed by Sadagopan Raghavan; M.Abdul Rasheed

Publisher: Elsevier Science
Year: 2003
Tongue: English
Weight: 157 KB
Volume: 14
Category: Article
ISSN: 0957-4166
DOI: 10.1016/s0957-4166(03)00239-8

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✦ Synopsis

A novel and stereospecific synthesis of (2R,3S)-3-amino-2-hydroxy-4-phenylbutanoate (AHPBA) is disclosed. The key step includes regio-and stereospecific functionalization of an alkene by the pendant sulfinyl group.

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