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Sulfene mechanism in the pyridine-catalysed reactions of alkanesulfonyl halides with phenols

✍ Scribed by Lyashchuk, Serge N.; Skrypnik, Yuri G.; Besrodnyi, Vladimir P.

Book ID
120328947
Publisher
Royal Society of Chemistry
Year
1993
Tongue
English
Weight
775 KB
Volume
6
Category
Article
ISSN
1472-779X

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## Abstract The reactivity of the lithium halides in 83.3% pyridine‐dimethylformamide changes from Cl^βˆ’^ > Br^βˆ’^ > I^βˆ’^ to Br^βˆ’^ > I^βˆ’^ to Br^βˆ’^ > I^βˆ’^ > Cl^βˆ’^ with increasing concentration of the salt from 0 to 0.35 M. This behaviour is explained by ion pairing which reduces the concentration of r