Sulfated and Phosphated Mesoporous Nb Oxide in the Benzylation of Anisole and Toluene by Benzyl Alcohol
β Scribed by Rao, Yuxiang; Trudeau, Michel; Antonelli, David
- Book ID
- 121318712
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 70 KB
- Volume
- 128
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The catalytic activity of gel and macroreticular ion-exchange resins (Lewatit and Amberlyst-15) was evaluated for the reaction of benzene with benzyl alcohol and benzyl chloride at 80Β°C in the liquid phase. With benzyl chloride, the monobenzylation product, diphenylmethane, was obtained in low yield
Permanganate, solubilized in methylene chloride with the aid of a phase transfer agent, oxidizes benzyl alcohol to benzaldehyde and bcnzyl ethers to benzoate esters. Although the rate of oxidation of the ether is about an order of magnitude slower than alcohol oxidation, both respond in an identical