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Sulfanyl- and Selanyldifluoromethylphosphonates as a Source of Phosphonodifluoromethyl Radicals and Their Addition onto Alkenes†

✍ Scribed by Lequeux, Thierry; Lebouc, Fanny; Lopin, Chrystel; Yang, Hongli; Gouhier, Géraldine; Piettre, Serge R.

Book ID
115487489
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
115 KB
Volume
3
Category
Article
ISSN
1523-7060

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📜 SIMILAR VOLUMES

ChemInform Abstract: Sulfanyl- and Selan
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A Study of Vinyl Radical Cyclization ont
A Study of Vinyl Radical Cyclization onto the Azido Group by Addition of Sulfanyl, Stannyl, and Silyl Radicals to Alkynyl Azides☆
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Thermal radical reactions of azidoalkynes 2, 8, 14, and 21ac with thiols 1a-c afford 2-sulfanylvinyl radicals by selective addition of sulfanyl radicals to the triple bond. 1-Phenylvinyl radicals 23 and 30a, as well as vinyl radical 30b, undergo fast 5-cyclization onto the aromatic azide function to