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Sugarometallic chemistry: Aglycone-chromium complex as chiral auxiliary in asymmetric Diels-Alder reaction

✍ Scribed by Tony K.M. Shing; Hak-Fun Chow; Ivan H.F. Chung

Book ID
103404690
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
217 KB
Volume
37
Category
Article
ISSN
0040-4039

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AbstractÐA new synthetic method is developed for the asymmetric Diels±Alder reactions of acetylenic dienophiles. Acetylenic Fischer carbene complexes with chiral pyrrolidines as the heteroatom stabilizing substituent were anticipated to block three of the four possible approaches of a diene and lead