The cquivalcncc of classical microcanonical vibrational sudden and adiabatic transition state theory is established. An optimal coordinate system for the sudden theory is defined by periodic orbit dividing surfaces.
Sudden approximation theory of vibrational excitation
β Scribed by Joel M. Bowman
- Book ID
- 104579748
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 626 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0020-7608
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π SIMILAR VOLUMES
Calculations of cross sections and rate constants are reported for the vibrationti relaution of CO in collision sith 3He and 4He. Results computed using a semiclassical technique and a vibrational close-coupling. rotational infmitearder sudden method are compared.
In this paper a three-dimensional quantum model to study vibrational predissociation of van der Waals molecules is applied to the +-He complex for very high vibrational (SO 4 ~14 64) of the 12 subunit The vibrations are described in the distorted-wave diabatic approximation while rotations are treat