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Successive electron transfer reaction of the lithium salt of 5-methyl-5,10-dihydrophenazine anion with 4-nitrophenethyl bromide via 4-nitrostyrene

✍ Scribed by Akira Sugimoto; Hideyuki Maruyama; Wataru Takahashi; Kazuhiko Mizuno; Kaku Uehara; Tomohiro Adachi

Publisher
Journal of Heterocyclic Chemistry
Year
1999
Tongue
English
Weight
472 KB
Volume
36
Category
Article
ISSN
0022-152X

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✦ Synopsis

Abstract

The reaction of lithium salt of 5‐methyl‐5,10‐dihydrophenazine anion with 4‐nitrophenethyl bromide in 1,2‐dimethoxyethane gave unexpected compounds, 1,2‐bis[5‐(10‐methyl‐5,10‐dihydrophenazinyl)]‐1‐(4‐nitrophenyl)ethane and 1,4‐bis(4‐nitrophenyl)‐1,4‐bis[5‐(10‐methyl‐5,10‐dihydrophenazinyl)]butane, while the reaction in dimethyl sulfoxide brought about the formation of 5‐methyl‐10‐(4‐nitrophenethyl)‐5,10‐dihydrophenazine. The successive electron transfer mechanism is proposed for the former reaction via 4‐nitrostyrene.

📜 SIMILAR VOLUMES

ChemInform Abstract: Successive Electron
ChemInform Abstract: Successive Electron Transfer Reaction of the Lithium Salt of 5-Methyl-5,10-dihydrophenazine Anion with 4-Nitrophenethyl Bromide via 4-Nitrostyrene.
✍ Akira Sugimoto; Hideyuki Maruyama; Wataru Takahashi; Kazuhiko Mizuno; Kaku Uehar 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 1 views

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