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Substrate Effects and Chemical State Plots for the XPS Analysis of Supported TiO2 Catalysts

✍ Scribed by Jiménez, V. M.; Lassaletta, G.; Fernández, A.; Espinós, J. P.; González-Elipe, A. R.


Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
231 KB
Volume
25
Category
Article
ISSN
0142-2421

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✦ Synopsis


The analysis by XPS of deposited on di †erent substrates MgO, Ag, SnO) shows the existence of TiO 2 (SiO 2 , shifts in the Ti 2p binding energy and Auger parameter values. The magnitude of these shifts is a function of the support and of the coverage. A systematic representation of these shifts is possible with a chemical state plot. The implications of the existence of such shifts for the characterization of catalysts are discussed.

1997 by John ( Wiley & Sons, Ltd.