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Substrate dependent ligand acceleration in enantioselective hydrogenation of (E)-2,3-diarylpropenoic acid on cinchonidine-modified Pd/C

✍ Scribed by Mameda, Takuya; Nakai, Kengo; Misaki, Tomonori; Okamoto, Yasuaki; Sugimura, Takashi

Book ID: 122259583
Publisher: Elsevier Science
Year: 2015
Tongue: English
Weight: 753 KB
Volume: 245
Category: Article
ISSN: 0920-5861
DOI: 10.1016/j.cattod.2014.03.075

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## Abstract The enantioselective hydrogenation of methoxy‐ and fluorine‐substituted (__E__)‐2,3‐diphenylpropenoic acid derivatives was studied over cinchonidine‐modified, supported palladium catalysts in the absence and presence of benzylamine as additive. The fluorine substituent in the appropriat