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Substrate-Controlled Palladium-Catalyzed Allylic Alkylations of Chelated Enolates – Scope and Limitations

✍ Scribed by Thomas Lindner; Uli Kazmaier


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
163 KB
Volume
347
Category
Article
ISSN
1615-4150

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Palladium-Catalyzed Diastereoselective a
✍ Manfred Braun; Thorsten Meier; Frank Laicher; Panos Meletis; Mesut Fidan 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 297 KB 👁 2 views

## Abstract Lithium and magnesium enolates of cyclohexanone undergo palladium‐catalyzed allylic alkylations under mild conditions. Diastereoselectivity and enantioselectivity are observed when the diphenyl‐ and dimethyl‐substituted allylic substrates **1a** and **1b** are reacted with cyclohexanone