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Substrate and Solvent Influence on the Photochemical C−H Bond Activation Reactivity of (HBPz‘ 3 )Rh(CO) 2 (Pz‘ = 3,5-Dimethylpyrazolyl)

✍ Scribed by Purwoko, Agus A.; Tibensky, Stephen D.; Lees, Alistair J.


Book ID
126440263
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
220 KB
Volume
35
Category
Article
ISSN
0020-1669

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The reactions of the bis(trimethylsilyl)acetylene permethylmetallocene complexes Cp 2 M(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (1), M = Zr (2)) with H 2 O and CO 2 were studied and compared to those of the corresponding metallocene complexes Cp 2 M(L)(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (3), L = ± ; M = Zr,