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Substitution reactions of vinylmercurials by a free-radical chain mechanism

โœ Scribed by Russell, Glen A.; Hershberger, James

Book ID
120219522
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
271 KB
Volume
102
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES

Free radical substitution reactions of p
Free radical substitution reactions of phenylacetylene derivatives by an addition-elimination mechanism
โœ Glen A Russell; Preecha Ngoviwatchai ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 190 KB

Sumary: Phenylacetylenes (PhCXQ with Q = PhS02, I, SPh, 8u3Sn PhC$Hg) undergo free radical chain substitution reactions with RHgCl, R2Hg, (Et0)2P(O)HgCl, (PhS)2Hg or (PhS02)2Hg. The relative reactivities of PhCXQ towards c-C6HII\* are Q = PhS02 (65) > I (19) > Bu3Sn (1.0).