Substitution reactions of a .mu.-thioether ligand in dinuclear cyclopentadienylmolybdenum complexes
โ Scribed by Tucker, D. S.; Dietz, S.; Parker, K. G.; Carperos, V.; Gabay, J.; Noll, B.; Rakowski DuBois, M.; Campana, Charles F.
- Book ID
- 125999880
- Publisher
- American Chemical Society
- Year
- 1995
- Tongue
- English
- Weight
- 1022 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0276-7333
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## Abstract A trinuclear carbonylruthenium complex, [Ru~3~(CO)~12~], was treated with diynes bearing ester, phenyl, or trimethylsilyl groups on the alkyne termini to give rise to various complexes. A diyne diester afforded a dinuclear ruthenacycle complex similar to known iron ferrole complexes and
Base hydrolysis reactions of [Cr(tmpa)(NCSe)] 2 O 2ฯฉ , [Cr(tmpa)(N 3 )] 2 O 2ฯฉ , and follow the pseudo-first-4ฯฉ 2ฯฉ [Cr (tmpa) (ฯชO)(ฯชPhPO )] [ Cr (tmpa) (ฯชO)(ฯชCO )] 2 2 4 2 2 3 order relationship (excess OH ฯช ): For the com- obsd o b p p 3 plex, ฯช2 ฯช1 k (60ะC) ฯญ (1.50 ฯฎ 0.03) ฯซ 10 s ; โฌH โก ฯญ 61 ฯฎ