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Substitution effect on phenalenyl backbone in the rate of organozinc catalyzed ROP of cyclic esters

โœ Scribed by Sen, Tamal K. ;Mukherjee, Arup ;Modak, Arghya ;Mandal, Swadhin K. ;Koley, Debasis


Book ID
119950936
Publisher
Royal Society of Chemistry
Year
2013
Tongue
English
Weight
589 KB
Volume
42
Category
Article
ISSN
1477-9226

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Decarbalkoxylations of geminal diesters
โœ A.Paul Krapcho; E.G.E. Jahngen Jr.; A.J. Lovey; Franklin W. Short ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 218 KB

Recently Krapcho and Lovey have reported that germinal diesters, B-keto esters and a-cyano esters undergo decarbalkoxylatlons when heated with sodium chloride In wet dimethyl eulfoxide at temperatures of 140-185' (1). We now wish to report further experiments addressed to the question of whether add