Substitution and oxidative addition reactions of platinum(0) complexes. Evidence for coordinatively unsaturated species in solution and as reactive intermediates

Oxidative Addition of α-Bromoglycine to

Oxidative Addition of α-Bromoglycine to Palladium(0) and Platinum(0) Complexes: α-Metallated Amino Acids as Models for Intermediates in the Metal-Catalyzed Hydrogenation of Dehydroamino Acids

✍ Bernd Kayser; Christopher Missling; Jörg Knizek; Heinrich Nöth; Wolfgang Beck 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 571 KB

Oxidative addition of methyl N-benzoyl-2-bromoglycinate to complexes [(bpy)PdϪCH(CO 2 Me)NHC(Ph)O] + (1b,c) and [(Ph 3 P) 2 PtϪCH(CO 2 Me)NHC(Ph)O] + (2b), respectively, fea-bis(dibenzylideneacetone)palladium, in the presence of 2,2Јbipyridyl, and to (Ph 3 P) 2 Pt(η 2 -C 2 H 4 ) gives the α-metallat