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Substituted βγ-Diphenyladipic Acids and Derivatives of Chrysene

✍ Scribed by VOGEL, A. I.


Book ID
109501682
Publisher
Nature Publishing Group
Year
1933
Tongue
English
Weight
109 KB
Volume
131
Category
Article
ISSN
0028-0836

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Catalytic asymmetric hydrogenation of β-
✍ Mark J. Burk; Karen M. Bedingfield; William F. Kiesman; John G. Allen 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 263 KB

The Rh-DuPHOS and Rh-BPE catalyzed hydrogenation of IS-substituted ¢x,[~,y,8-unsaturated amino acids establishes two contiguous stereogenic centers simultaneously. Both high regioselectivity and good to excellent enantioselectivity have been demonstrated in this process leading to I~-branched allyl