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Substituted 2,4,6-triamino-1,3,5-thiadiazinium salts. A new heteroaromatie system

✍ Scribed by James E. Oliver; Albert B. Demilo


Book ID
112122565
Publisher
Journal of Heterocyclic Chemistry
Year
1971
Tongue
English
Weight
175 KB
Volume
8
Category
Article
ISSN
0022-152X

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A new, three-stage synthesis of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) has been developed which avoids the use of halogenated precursors or reagents. The starting material, 1,3,5trihydroxy-benzene, is converted via the sequence nitrationalkylation-amination to TATB in an overall yield of 87%. T