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Substituted 2-Pyrones and 5,6-Dihydropyrones

โœ Scribed by William C. Groutas; Tien L. Huang; Michael A. Stanga; Michael J. Brubaker; Min K. Moi


Book ID
112127814
Publisher
Journal of Heterocyclic Chemistry
Year
1985
Tongue
English
Weight
168 KB
Volume
22
Category
Article
ISSN
0022-152X

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A novel route to 6-substituted and 5,6-d
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6-Alkyl-and 6-(1-alkenyl)-5-iodo-2-pyrones, which are available as major products by reaction of the corresponding (Z)-2-en-4-ynoic acids with iodine and NaHCO 3 in CH 3 CN, undergo insertion of activated zinc metal into their carbon iodine bond to provide the corresponding 5-(iodozinc)-2-pyrones. H