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Substituent Increments for the 1H-NMR. Chemical Shifts of the 18- and 19-Methyl Protons of Steroids. Part I: 9β, 10α(Retro)-Steroids

✍ Scribed by Gerhard Englert; Wolf Arnold; Hans Els; Andor Fürst; Arthur Meier; Walter Meister


Publisher
John Wiley and Sons
Year
1974
Tongue
German
Weight
512 KB
Volume
57
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

This paper reports 261 substituent increments for the ^1^HNMR. chemical shifts (solvent: CDCl~3~) of the 18‐ and 19‐methyl protons of 9β, 10α(retro)‐steroids relative to 5β,9β,10α,‐androstane. The increments were calculated by a least‐squares procedure from 1334 spectra of 759 different steroids.


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Substituent Increments for the 1H-NMR. C
✍ Wolf Arnold; Walter Meister; Gerhard Englert 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 German ⚖ 387 KB

## Abstract In Part II of this series we report 292 substituent increments for the ^1^H‐NMR. chemical shifts (solvent: CDCl~3~) of the 18‐ and 19‐methyl protons of 9α,10β(normal)‐steroids relative to 5α,9α,10β,‐androstane. The increments were calculated by a least‐squares procedure from 988 spectra