This review summarises attempts that have been made to quantify and separate steric and electronic factors associated with zirconocene-type catalysts in the olefin polymerisation reaction. The use of cone and solid angles, measurement of molecular spaces (coordination gap aperture, obliquity angle a
β¦ LIBER β¦
Substituent effects on titanocenium catalysts
β Scribed by Andreas Kucht; Homa Kucht; Wei Song; Marvin D. Rausch; James C. W. Chien
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 478 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0268-2605
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## Abstract Olefin polymerizations were conducted with novel multimetallic zirconocene catalyst systems: Rο£ΏCpCpZrCl~2~ (1) (R = dimethylsilylferrocene; Cp = cyclopentadienyl) and (Rο£ΏCp)~2~ZrCl~2~ (2) in combination with methylaluminoxane or tetrakis(pentafluorophenyl) borates. In ethylene polymeriz
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