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Substituent Effects on Thermochemical Properties of C-, N-, O-, and S-Centered Radicals. Physical Interpretation of Substituent Effects

โœ Scribed by Cherkasov, A.; Jonsson, M.

Book ID
126918916
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
53 KB
Volume
39
Category
Article
ISSN
0095-2338

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The aniline molecule is nonplanar, with its NH 2 group lying at an angle ฮธ of approximately 42 โ€ข to the plane of the benzene ring. Substituents on the phenyl ring alter this out-of-plane angle as well as other molecular properties such as the ring bond lengths and angles, the barrier to inversion E