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Substituent effects on the stability of carbocations. Anomalous case of phenyl vs. cyclopropyl substitution

✍ Scribed by Wolf, J. Frederick; Harch, Paul G.; Taft, Robert W.; Hehre, Warren J.


Book ID
126848993
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
401 KB
Volume
97
Category
Article
ISSN
0002-7863

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Substituent effects on the mass spectra
✍ A. A. Gamble; J. R. Gilbert; J. G. Tillett πŸ“‚ Article πŸ“… 1971 πŸ› John Wiley and Sons 🌐 English βš– 344 KB

The mass spectra of a series of mefa-and para-substituted phenyl acetates have been examined. Substituent effects have been correlated with A(AP-IP) values and by using the Harrison and Chin approach. The bond-cleavage and rearrangement reactions of phenyl acetates are compared with the correspondin